Interfacial adhesion of nanoparticles in polymer blends by intrinsic fluorescence spectra

Interfacial slip in sheared polymer blends.

We have developed a dynamic self-consistent field theory, without any adjustable parameters, for unentangled polymer blends under shear. Our model accounts for the interaction between polymers, and enables one to compute the evolution of the local rheology, microstructure, and the conformations of the polymer chains under shear self-consistently. We use this model to study the interfacial dynam...

Interfacial segregation in polymer blends driven by acid-base interactions.

Infrared-visible sum frequency generation spectroscopy (SFG) was used to measure the interfacial concentrations of poly(methyl methacrylate) (PMMA)/polystyrene (PS) blends next to a sapphire substrate. The acid-base interactions of carbonyl groups of PMMA with the hydroxyl groups on the sapphire drive the interfacial segregation of PMMA next to the sapphire substrate. Using the shift of sapphir...

control of the optical properties of nanoparticles by laser fields

در این پایان نامه، درهمتنیدگی بین یک سیستم نقطه کوانتومی دوگانه(مولکول نقطه کوانتومی) و میدان مورد مطالعه قرار گرفته است. از آنتروپی ون نیومن به عنوان ابزاری برای بررسی درهمتنیدگی بین اتم و میدان استفاده شده و تاثیر پارامترهای مختلف، نظیر تونل زنی(که توسط تغییر ولتاژ ایجاد می شود)، شدت میدان و نسبت دو گسیل خودبخودی بر رفتار درجه درهمتنیدگی سیستم بررسی شده اشت.با تغییر هر یک از این پارامترها، در...

Controlling the Assembly of Nanoparticles in Polymer Blends

Linear viscoelasticity of incompatible polymer blends in the melt in relation with interfacial properties

A quite general characteristic of the rheology of incompatible polymer blends in the melt is their highly elastic behaviour at low frequencies, corresponding to long-time relaxation processes. For emulsions of Newtonian liquids, this property can be readily connected to interfacial tension a: in a macroscopic flow, suspended droplets of radius R are subjected on the one hand to a viscous drag r...